Alternating ring-opening metathesis polymerization by Grubbs-type catalysts with N-pentiptycenyl, N-alkyl-NHC ligands†
Roman Vasiuta,Alexander Stockert,Herbert Plenio
Chemical Communications Pub Date : 12/08/2017 00:00:00 , DOI:10.1039/C7CC08476E
Abstract
A Grubbs–Hoveyda type catalyst with a N-pentiptycenyl, N-cyclohexyl-NHC ligand provides poly(nbe-alt-coe) with an excellent degree of alternation while lacking significant activity in the homopolymerization of cyclooctene.
