Anti-Markovnikov hydrophosphoroselenoylation of alkenes using phosphorodiselenoic acid esters leading to the formation of phosphonoselenoic acid esters†,10.1039/C3CC45912H

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Anti-Markovnikov hydrophosphoroselenoylation of alkenes using phosphorodiselenoic acid esters leading to the formation of phosphonoselenoic acid esters†

Yuuki Maekawa,Masaki Monzaki,Takafumi Ando,Toshifumi Maruyama

Chemical Communications Pub Date : 08/21/2013 00:00:00 , DOI:10.1039/C3CC45912H

Abstract

Phosphorodiselenoic acid esters with a binaphthyl group were reacted with alkenes in the presence of Bu₃SnH and AIBN to give phosphonoselenoic acid esters in moderate to good yields. The addition of a phosphoroselenoyl group to alkenes proceeded in an anti-Markovnikov fashion. The diastereoselectivity was improved by the introduction of substituents to 3,3′-positions of a binaphthyl group.