An approach towards expanding the scope of masked o-benzoquinone dimers to generate diverse compound libraries†‡,10.1039/C5RA03627E

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An approach towards expanding the scope of masked o-benzoquinone dimers to generate diverse compound libraries†‡

Santhosh Kumar Chittimalla,Shoba Laxmi,Amerlyn Chong Ming Liing,Jerald Lam Kai Jun,Rajesh Kuppusamy,Sireesha Putturu,Chennakesavulu Bandi

RSC Advances Pub Date : 03/25/2015 00:00:00 , DOI:10.1039/C5RA03627E

Abstract

In this report, a simple and rapid approach for the synthesis of masked o-benzoquinone (MOB) heterodimers is presented. Appropriately substituted 2-methoxyphenols were converted to MOB homodimers which were then transformed to MOB heterodimers utilizing either vinylic substitution (via addition-elimination) reaction protocol or organometallic reaction procedures.