An easy access to tertiary amides from aldehydes and N,N-dialkylchlorothiophosphoramidates†,10.1039/C3RA45781H

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An easy access to tertiary amides from aldehydes and N,N-dialkylchlorothiophosphoramidates†

Uma Pathak,Shubhankar Bhattacharyya,Lokesh kumar Pandey,Sweta Mathur,Rajeev Jain

RSC Advances Pub Date : 10/31/2013 00:00:00 , DOI:10.1039/C3RA45781H

Abstract

A mechanistically unprecedented approach for the formation of tertiary amides from N,N-dialkylchlorothiophosphoramidates and aldehydes has been developed. The reaction occurred via the activation of aldehydes with N,N-dialkylchlorothiophosphoramidates followed by amidation with dialkylamine pendent of the same phosphoramidate.