A number of transition metal hydrides reveal intriguing temperature-dependent J_HD in their deuterated derivatives and possibly the temperature dependent hydrogen–hydrogen distance (r(H–H)) as well. Previously, theoretical studies rationalized J_HD and r(H–H) changes in such compounds through a “temperature-elastic” structure model with a significant population of vibrational states in an anharmonic potential. Based on the first variable temperature neutron diffraction study of a relevant complex, (p-H-POCOP)IrH₂, observation of its elusive counterpart with longer r(H–H), crystallized as an adduct with C₆F₅I, and thorough spectroscopic and computational study, we argue that the model involving isomeric species in solution at least in some cases is more relevant. The existence of such isomers is enabled or enhanced by solvation and weak non-covalent interactions with solvent, such as halogen or dihydrogen bonds. “Non-classical” hydrides with r(H–H) ≈ 1.0–1.6 Å are especially sensitive to the above-mentioned factors.