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Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect†
Ming-Feng Qin,Chang-Yu Wang,Song-Song Bao,Li-Min Zheng
Chemical Communications Pub Date : 06/28/2022 00:00:00 , DOI:10.1039/D2CC02470E
Abstract

A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing a metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10−3 S·cm−1 at 25 °C and 95% RH, a photothermal effect over a wide spectral range from UV-vis to NIR, and photo-enhanced and switchable proton conductivity.

Graphical abstract: Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect
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