Organoboranes obtained from hydroboration reactions are one of the important classes of compounds that could be used to provide valuable synthons for follow-up transformations such as various functional group incorporation or C–C bond forming reactions. For decades, various transition metals were utilised as catalysts in such transformations. Recently Earth-abundant and less toxic main group metals have revived their importance in hydroboration chemistry, among which the suitable candidates are aluminium complexes as catalysts. In this regard, the development of aluminium complexes to achieve more robust catalytic systems with greater efficiency is appreciable.