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Iron(ii) complexes supported by pyrazolyl-substituted cyclopentadienyl ligands: synthesis and reactivity†
Pokpong Rungthanaphatsophon,Nigam P. Rath,Jamie M. Neely
Dalton Transactions Pub Date : 02/22/2022 00:00:00 , DOI:10.1039/D2DT00199C
Abstract

The preparation of bis(pyrazolyl)cyclopentadienyl iron complexes is described. Isopropyl substitution promotes solubility of the iron chloride complex that serves as a precursor to several derivatives through ligand exchange. Modification of the cyclopentadienyl substituent to replace a pyrazolyl unit with a phenyl group favors formation of a substituted ferrocene complex.

Graphical abstract: Iron(ii) complexes supported by pyrazolyl-substituted cyclopentadienyl ligands: synthesis and reactivity
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