The emergence of the COVID-19 pandemic and airborne particulate matter pollution have caused a surge in the consumption of face masks in recent years. Typically, face masks are made from nondegradable petroleum-derived nonwoven materials adding to global plastic pollution and aggravating environmental concerns. Therefore, it is important to fabricate sustainable biodegradable replacements. This review intends to highlight and discuss state-of-the-art research activities that centre on the development of biodegradable nonwoven materials for face mask applications. We also identify potential candidates and strategies for future research and product development efforts. Finally, we present our perspectives on a wide avenue in need of further exploration concerning materials, methods, advanced functionalities, cost, scalability, and shelf life of sustainable advanced face masks.