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A BODIPY/pyridine conjugate for reversible fluorescence detection of gold(iii) ions†
Muhammed Üçüncü,Erman Karakuş,Mustafa Emrullahoğlu
New Journal of Chemistry Pub Date : 08/13/2015 00:00:00 , DOI:10.1039/C5NJ01664A
Abstract

We designed a “turn-on” type fluorescent probe based on a BODIPY–pyridine conjugate which exhibits high selectivity towards Au(III) ions and, also responds to changes in the pH within the acidic pH range. The probe offers features such as a rapid response time, a low detection limit, and high sensitivity and selectivity. The detection of Au(III) is recognized by a distinct change in the emission intensity which relies on a reversible “ligand to ion” binding mechanism. We also document the utility of the probe for the quantification of gold ion residues in synthetic end products prepared via gold catalysis.

Graphical abstract: A BODIPY/pyridine conjugate for reversible fluorescence detection of gold(iii) ions
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