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An ionic liquid as a green solvent for high potency synthesis of 2D covalent organic frameworks†
Limin Zhao,Huimin Liu,Yue Du,Xiang Liang,Wenju Wang,Hui Zhao,Wenzhi Li
New Journal of Chemistry Pub Date : 08/14/2020 00:00:00 , DOI:10.1039/D0NJ01478H
Abstract

Covalent organic frameworks (COFs) are emerging crystalline porous materials with a wide range of potential applications. However, optimizing the synthesis process and green synthesis COFs is still a challenge. Here, we report a simple strategy to synthesize two-dimensional covalent organic frameworks (2D COFs) using ionic liquids (ILs) as green solvents. By using the same ILs, 2D keto-enamine-linked COFs and polyimide COFs can be obtained through similar reaction conditions. The structure of the as-synthesized COFs is proved with PXRD, IR and 13C NMR. The prepared COFs display good crystallinity and high thermal stability. This strategy provides a potential way for the green synthesis of 2D COFs.

Graphical abstract: An ionic liquid as a green solvent for high potency synthesis of 2D covalent organic frameworks
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