[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(ii) catalyst for propargylic substitution and isomerization of HCCCPh2(OH)†,10.1039/B410812D

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(ii) catalyst for propargylic substitution and isomerization of HCCCPh2(OH)†

Victorio Cadierno,Josefina Díez,Sergio E. García-Garrido,José Gimeno

Chemical Communications Pub Date : 10/14/2004 00:00:00 , DOI:10.1039/B410812D

Abstract

The 16e⁻ derivative [Ru(η³-2-C₃H₄Me)(CO)(dppf)][SbF₆] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.