Converting CO₂ to renewable fuels or valuable carbon compounds is an effective way to solve the global warming and energy crisis. Compared with other CO₂ conversion methods, photocatalytic reduction of CO₂ is more energy-saving, environmentally friendly, and has a broader application prospect. Layered double hydroxide (LDH) has attracted widespread attention as a two-dimensional material, composed of metal hydroxide layers, interlayer anions and water molecules. This review briefly introduces the basic theory of photocatalysis and the mechanism of CO₂ reduction. The composition and properties of LDH are introduced. The research progress on LDH in the field of photocatalytic reduction of CO₂ is elaborated from six aspects: directly as a catalyst, as a precursor for a catalyst, and by modification, intercalation, supporting with other materials and construction of a heterojunction. Finally, the development prospects of LDH are put forward. This review could provide an effective reference for the development of more efficient and reasonable photocatalysts based on LDH.