Ligand-directed structure evolution from a titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti3O} units†
Min Meng,Lingrong Liao,Qi Zheng,Weimin Xuan
New Journal of Chemistry Pub Date : 05/11/2023 00:00:00 , DOI:10.1039/D3NJ01172K
Abstract
By modulating the geometry and size of the ligand and using phosphite as a bridging linker, {Ti3(μ3-O)} can be assembled into a discrete {Ti6} cluster, coordination capsule {Ti18Cu3} and one-dimensional coordination polymer {Ti6}n.
