An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst†,10.1039/D2NJ03136A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst†

Congjian Ni,Hailong Yu,Ling Liu,Ben Yan,Bingyi Zhang,Xiaoli Ma,Xiuhui Zhang,Zhi Yang

New Journal of Chemistry Pub Date : 07/13/2022 00:00:00 , DOI:10.1039/D2NJ03136A

Abstract

A cheap and easily available ZnEt₂ is an effective precatalyst, which can be used for the hydroboration reaction of various organic carbonates and esters with HBpin. The preliminary hydroboration reaction mechanism has been investigated via the corresponding DFT calculation.