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Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions†
Tatsuya Morofuji,Takuma Kurokawa,Naokazu Kano
Organic & Biomolecular Chemistry Pub Date : 11/16/2022 00:00:00 , DOI:10.1039/D2OB02055F
Abstract

In this study, we propose that the trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF3)2]IPN is a versatile organic photocatalyst that can be used for electron-transfer-driven reactions requiring a photocatalyst with high oxidizing power and energy-transfer-driven reactions that require an Ir photocatalyst. 4[Cz(CF3)2]IPN was used in radical reactions via electron transfer and dearomative cycloaddition reactions via energy transfer.

Graphical abstract: Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions
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