960化工网
An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}†
Han-Rui Tian,Wen-Hua Wang,Xiao-Ping Zhang,Yun-Long Feng,Jian-Wen Cheng
Dalton Transactions Pub Date : 11/15/2012 00:00:00 , DOI:10.1039/C2DT32364H
Abstract

A new 3D lead borate Pb6B6O14(OH)2(H2O), built by different cluster building units of B6O14(OH) {B6} and Pb6O5(OH) {Pb6}, has been obtained under mild hydrothermal conditions. Each {B6} cluster is linked with seven {Pb6} clusters and vice versa that give rise to the first 7-connected lead borate network.

Graphical abstract: An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}
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