960化工网
Heterogeneous photochemical reaction enabled by an ultrasonic microreactor†
Aniket P. Udepurkar,Kakasaheb Y. Nandiwale,Klavs F. Jensen,Simon Kuhn
Reaction Chemistry & Engineering Pub Date : 04/24/2023 00:00:00 , DOI:10.1039/D3RE00154G
Abstract

The presence of solids as starting reagents/reactants or products in flow photochemical reactions can lead to reactor clogging and yield reduction from side reactions. We address this limitation with a new ultrasonic microreactor for continuous solid-laden photochemical reactions. The ultrasonic photochemical microreactor is characterized by the liquid and solid residence time distribution (RTD) and the absorbed photon flux in the reactor via chemical actinometry. The solid-handling capability of the ultrasonic photochemical microreactor is demonstrated with a silyl radical-mediated metallaphotoredox cross-electrophile coupling with a solid base as a reagent.

Graphical abstract: Heterogeneous photochemical reaction enabled by an ultrasonic microreactor
平台客服
平台客服
平台在线客服