Epoxy-based polymer networks from step-growth polymerizations are ubiquitous in coatings, adhesives, and as matrices in composite materials. Dynamic covalent bonds in the network allow its degradation into small molecules and thus, enable chemical recycling; however, such degradation often requires elevated temperatures and costly chemicals, resulting in various small molecules. Here, we design crosslinked polyesters from structurally similar epoxy and anhydride monomers derived from phthalic acid. We achieve selective degradation of the polyesters through transesterification reactions at near-ambient conditions using an alkali carbonate catalyst, resulting in a singular phthalic ester. We also demonstrate upcycling the network polyesters to photopolymers by one-step depolymerization using a functional alcohol.