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Assessment of the mechanical suppression of nonuniform electrodeposition in lithium metal batteries
Shuenn-Jyh Chang,Chih-Hung Chen,Kuo-Ching Chen
Physical Chemistry Chemical Physics Pub Date : 04/08/2022 00:00:00 , DOI:10.1039/D1CP05310H
Abstract

Dendrite formation is a long-standing issue in lithium metal batteries. Replacing the conventional liquid electrolytes with semi-solid ones, the non-uniform lithium growth can be potentially mitigated by the mechanical deformation in the solid matrix. The underlying dendrite suppression mechanism is investigated in this study using a mechano-electrochemical phase-field method. Two indicators, namely the arithmetic average height and the elongation rate, are proposed to characterize the surface roughness of lithium dendrites. Our simulation results are summarized in two-dimensional design maps as a function of the porosity and the elastic modulus of the semi-solid electrolytes, which could provide us the guidance for the development of dendrite-free lithium metal batteries.

Graphical abstract: Assessment of the mechanical suppression of nonuniform electrodeposition in lithium metal batteries
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