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Cinchona alkaloids – acid, anion-driven fluorescent INHIBIT logic gates with a receptor1–fluorophore–spacer–receptor2 format and PET and ICT mechanisms
Nicola' Agius,David C. Magri
RSC Advances Pub Date : 05/02/2023 00:00:00 , DOI:10.1039/D3RA02704J
Abstract

The fluorescent natural products, quinine, quinidine, cinchonine and cinchonidine are demonstrated as H+-enabled, halide-disabled (Cl, Br or I) INHIBIT and INHIBIT-OR combinatorial logic gates in water. More fluorescent natural products with intrinsic logic properties await to be discovered.

Graphical abstract: Cinchona alkaloids – acid, anion-driven fluorescent INHIBIT logic gates with a receptor1–fluorophore–spacer–receptor2 format and PET and ICT mechanisms
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