In this study, we successfully synthesized Ag@CuO@rGO (rGO wrapped around Ag/CuO) nanocomposites using AgNO₃, Cu(NO)₃₂, and NaOH as raw materials and particularly treated CTAB as a template by chemical precipitation, hydrothermal synthesis, and subsequent high-temperature calcination processes. In addition, transmission electron microscopy (TEM) images revealed that the prepared products appeared to have a mixed structure. The results indicated that the best choice was CuO wrapped around Ag nanoparticles to form a core–shell crystal structure, and the crystal particles were arranged similarly to form an icing sugar block structure and were tightly wrapped by rGO. Moreover, the electrochemical test results demonstrated that Ag@CuO@rGO composite electrode material exhibited high pseudocapacitance performance; the material had a high specific capacity of 1453 F g⁻¹ at a current density of 2.5 mA cm⁻², and the charging and discharging cycles remained constant up to 2000 times, indicating that the introduction of Ag improved the cycling stability and reversibility of the CuO@rGO electrode material and increased its specific capacitance, leading to the increase in the specific capacitance of supercapacitors. Therefore, the above results strongly support the application of Ag@CuO@rGO in optotronic devices.