960化工网
Controlled mechano-luminescence properties of SrGa2O4:Tb3+ co-doping with Dy3+ and Eu3+ ions†
Chaochao Wang,Zhichao Liu,Alexey Nikolaevich Yakovlev,Tingting Hu,Tatiana Grigorievna Cherkasova,Xiaodie Zhu,Ya Liu,Jian Zhang,Daiyuan Liu,Xue Yu
RSC Advances Pub Date : 05/31/2023 00:00:00 , DOI:10.1039/D3RA01985C
Abstract

Trap-controlled mechano-luminescence (ML) featuring photon emission under mechanical stimuli provides promising applications such as dynamic imaging of force, integrated optical sensing, information storage, and anti-counterfeiting encryption. However, the corresponding emission with a single color still limits the application of ML materials. Here, a trap-controlled ML phosphor of SrGa2O4:Tb3+ (SGO:Tb3+) with a green-emission is investigated with an adjustable ML color. The relationship between ML and thermoluminescence (TL) is verified by co-doping with Dy3+ and Eu3+ ions for the manipulation of the constructed traps. Accordingly, the as-explored ML phosphor with multicolor output is employed to create encrypted anticounterfeiting patterns, which produces bright and spatially resolvable optical codes under the single-point dynamic pressure of a ballpoint pen. Hence, it provides a new approach to achieve ML with multicolor and gives us an insight into understanding the mechanism of the ML procedure.

Graphical abstract: Controlled mechano-luminescence properties of SrGa2O4:Tb3+ co-doping with Dy3+ and Eu3+ ions
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