Fe(iii)-catalysed selective C–N bond cleavage of N-phenylamides by an electrochemical method†,10.1039/D2RA04709H

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Fe(iii)-catalysed selective C–N bond cleavage of N-phenylamides by an electrochemical method†

Yiwen Xu,Yang Long,Runyou Ye,Qiang Li,Fang Ke,Xiangge Zhou

RSC Advances Pub Date : 08/25/2022 00:00:00 , DOI:10.1039/D2RA04709H

Abstract

An Fe(III)-catalysed transformation of secondary N-phenyl substituted amides to primary amides by an electrochemical method is developed. Regioselective aryl C–H oxygenation occurs during the reaction, promoting selective C(phenyl)-N bond cleavage to form primary amides in yields of up to 92%.