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Mechanistic insights into the gold chemistry of allenes
Weibo Yang,A. Stephen K. Hashmi
Chemical Society Reviews Pub Date : 03/27/2014 00:00:00 , DOI:10.1039/C3CS60441A
Abstract

Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allenes which are based on computational studies, labelling studies, the detection of intermediates, chirality transfer and diastereoselective product formation.

Graphical abstract: Mechanistic insights into the gold chemistry of allenes
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