In situ2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules†,10.1039/C0CE00135J

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

In situ2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules†

Deyun Ma,Weixia Wang,Yingwei Li,Carole Daiguebonne,Guillaume Calvez,Olivier Guillou

CrystEngComm Pub Date : 08/13/2010 00:00:00 , DOI:10.1039/C0CE00135J

Abstract

A new microporous europium-containing metal–organic framework [Eu₂(μ₂-pzdc)(μ₄-pzdc)(μ₂-ox)(H₂O)₄]·8H₂O (1) (H₂pzdc = 2,5-pyrazinedicarboxylic acid, H₂ox = oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schläfli symbol of (4·6⁴·8)₂(4²·6²·8²), which exhibits a reversible and highly selective sensing function with respect to acetone.