The hydrogenation of phenol to cyclohexanol under mild conditions (∼340 K) was achieved over Raney Ni catalyst in the aqueous phase. The adsorption–desorption properties of the reactants (phenol and H2) and the products (cyclohexanone and cyclohexanol) on the Raney Ni catalyst are different in the aqueous phase and the organic phase. The hydrogenation rate of phenol is improved because the Raney Ni catalyst adsorbs more H2 and phenol in water than in methanol. Meanwhile, the higher uptakes of H2 and the lower desorption rates for cyclohexanone on the Raney Ni catalyst in the aqueous system result in the further hydrogenation of cyclohexanone to cyclohexanol.
