[Zn(H2O)4][Zn2Sn3Se9(MeNH2)]: a robust open framework chalcogenide with a large nonlinear optical response†
Manolis J. Manos,Joon I. Jang,John B. Ketterson,Mercouri G. Kanatzidis
Chemical Communications Pub Date : 12/18/2007 00:00:00 , DOI:10.1039/B712732D
Abstract
[Zn(H2O)4][Zn2Sn3Se9(MeNH2)] has an open polar framework based on supertetrahedral clusters with a unique double connectivity mode and exhibits a strong second harmonic generation response, excellent acid stability and proton exchange capacity.
![Graphical abstract: [Zn(H2O)4][Zn2Sn3Se9(MeNH2)]: a robust open framework chalcogenide with a large nonlinear optical response](http://hg.y866.cn/compound/lib/scimg/usr/1/B712732D.jpg)
