Ba2−xSrxPdO2F2
(0 ≤
x
≤ 1.5): The first palladium–oxide–fluorides†
Thomas Baikie,Emma L. Dixon,John F. Rooms,Nigel A. Young,M. Grazia Francesconi
Chemical Communications Pub Date : 05/29/2003 00:00:00 , DOI:10.1039/B303402J
Abstract
The first series of alkaline-earth palladium oxide–fluorides Ba2−xSrxPdO2F2 (0 ≤ x ≤ 1.5) display the T′ structure (Nd2CuO4) instead of the predicted T structure (La2CuO4), showing that electronic factors prevail over steric factors.
