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A carboxylic acid functionalized benzimidazole-based supramolecular gel with multi-stimuli responsive properties†
Hong Yao,Hong-Ping Wu,Jing Chang,Qi Lin,Tai-Bao Wei,You-Ming Zhang
New Journal of Chemistry Pub Date : 03/08/2016 00:00:00 , DOI:10.1039/C5NJ03422A
Abstract

A novel supramolecular gelator (C11) based on a carboxylic acid-functionalized benzimidazole was synthesized, which could form an organogel (C11-OG) and generate a metallogel (Pb-MG) with Pb2+. Both of the supramolecular gels exhibit aggregation-induced enhanced emission (AIEE). The Pb-MG shows outstanding reversible sol–gel transitions induced by the change in temperature, EDTA and Na2S. It has the potential to be widely applied in materials science.

Graphical abstract: A carboxylic acid functionalized benzimidazole-based supramolecular gel with multi-stimuli responsive properties
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