This study presents a gold nanoparticle (Au NP) system based on interaction between cyclam and Au NPs. We have found that in the presence of Cd²⁺, cyclam coated Au NPs form well defined wheel like supramolecular assembled nanostructures. Self-assembly is achieved via co-ordination bonding between cyclam decorated Au NPs and Cd²⁺ ions. This finding introduces novel assembled nanostructures and contributes to understand the effect of Cd²⁺ cyclam interaction on the morphology of Au NPs assembly.