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Exploring energy transfer between pyrene complexes and europium ions – potential routes to oxygen sensors†
Rebekka Hueting,Manuel Tropiano,Stephen Faulkner
RSC Advances Pub Date : 09/05/2014 00:00:00 , DOI:10.1039/C4RA09271F
Abstract

Pyrene chromophores are shown to exhibit reversible energy transfer to europium ions, resulting in oxygen dependent lanthanide luminescence. Two different pathways can give rise to oxygen dependence: rapid reversible energy transfer between the T1 state and the emissive state, or slow T15D0 energy transfer on the timescale of triplet state quenching.

Graphical abstract: Exploring energy transfer between pyrene complexes and europium ions – potential routes to oxygen sensors
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