Sn(iv) phosphonates as catalysts in solvent-free Baeyer–Villiger oxidations using H2O2†
Sharath Kirumakki,Sandani Samarajeewa,Robert Harwell,Atashi Mukherjee,Rolfe H. Herber,Abraham Clearfield
Chemical Communications Pub Date : 10/08/2008 00:00:00 , DOI:10.1039/B807938B
Abstract
We have designed a new family of layered Sn(IV)phosphonate (SnPP) materials which are very efficient catalysts in the BV oxidation of aromatic aldehydes without any solvent and using aqueous H2O2 (30%) as the oxidant.