First Example of Alkynyliodonium Tosylates coupling with 1,1-Bimetalloalkenes of Selenium and Zirconium
Journal of Chemical Research, Synopses Pub Date : , DOI:10.1039/A801589I
Abstract
Hydrozirconation of internal acetylenic selenides afforded 1,1-bimetalloalkenes, (E)-α-selanylvinylzirconium, which can cross-couple with alkynyliodonium tosylates directly in the presence of Pd(PPh3)4 as the catalyst.
