Solution-processed tandem polymer solar cells are demonstrated using stacked perovskite, (TBA,H)Ca₂Nb₃O₁₀ (CNO), semiconductor nanosheets as an electron transport layer (ETL) within the recombination layers. Two poly(3-hexylthiophene):(6,6)-phenyl-C₆₁-butyric acid methyl ester, P3HT:PCBM, sub-cells connected in series via a CNO–poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), Pedot:PSS, recombination layer provide a V_oc of 1.02 V. The V_oc is less than double that of a single junction due to leakage (dark) current. When TiO_x is used as an additional hole-blocking layer within the recombination stack, the V_oc is improved to 1.16 V. Although further optimization of the CNO-layer is still required, the use of CNO nanosheets within the recombination stack shows clear advantages. In addition to electron extraction from photoactive layers, the presence of defect states in the CNO nanosheets with trapped electrons facilitates the recombination of holes from Pedot:PSS, enhancing the function of the recombination stack. The robust CNO-layer can be spin-coated on top of a P3HT:PCBM bulk-heterojunction photoactive layer and is stable toward subsequent processing and heat-treatment.