960化工网
Growth of single-crystalline rutileTiO2nanorod arrays on GaN light-emitting diodes with enhanced light extraction†
Weijia Zhou,Zhengmao Yin,Xiaopeng Hao,Yongzhong Wu
Journal of Materials Chemistry Pub Date : 01/24/2012 00:00:00 , DOI:10.1039/C2JM14369K
Abstract

TiO2 is a wide band gap semiconductor with important applications in photovoltaic cells and photocatalysis. In this paper, single-crystalline rutileTiO2 nanorod arrays were fabricated on the GaN based light emitting diodes (LEDs) with a TiO2 seed layer by an acid hydrothermal process. The morphologies and the crystallinity of the rutileTiO2 nanorod arrays on GaN wafer were characterized by scanning electron microscopy, high-resolution transmission electron microscopy and X-ray diffraction. The optical properties of surface-textured TiO2/GaN were measured and analyzed by photoluminescence. The influence and dependence of the TiO2 nanorod array with the different densities and diameters on the light output of the fabricated GaN wafers were investigated. The light extraction efficiency of GaN LEDs was enhanced by the single-crystalline rutileTiO2 nanorod array, which showed an eight-fold increase in photoluminescence intensity compared to the normal planar surface. The mechanisms for the enhanced light output of GaN LEDs by the single-crystalline rutileTiO2 nanorod arrays were discussed.

Graphical abstract: Growth of single-crystalline rutileTiO2 nanorod arrays on GaN light-emitting diodes with enhanced light extraction
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