Electrochemical reactions. Part IV. The polarography of substituted benzyltriphenylphosphonium salts
Journal of the Chemical Society B: Physical Organic Pub Date : , DOI:10.1039/J29680000063
Abstract
The half-wave reduction potentials of a series of benzyltriphenylphosphonium salts substituted on the benzyl group show a linear correlation with Hammett σ-substituent values with ρ=+0·23 volts.