Gas phase reactions of sodium. Part III. Rates of reaction of allyl, propargyl, and cyanomethyl chloride
Journal of the Chemical Society B: Physical Organic Pub Date : , DOI:10.1039/J29660000042
Abstract
Bimolecular velocity constants have been measured for the reaction of allyl, propargyl, and cyanomethyl chloride with gaseous sodium. The results are discussed in terms of bond-dissociation energies and negative-group effects.