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An unusual stereoelectronic effect in the rearrangement of the Diels–Alder adducts of cyclopropene and furan
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700001353
Abstract

Cyclopropene formed the exo and endo Diels–Alder adducts in a 1 : 1 ratio with furan; only the endo-isomer readily rearranges to cycloheptadienones.

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