Uptake of carbon monoxide and oxygen by RhCl(CO)(PPh3)2 and catalytic oxidation of carbon monoxide and triphenylphosphine
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700000977
Abstract

The compounds Rh2Cl2(CO)4(II) and RhCl(CO)2(OPPh3)2(III) have been prepared from the reaction of RhCl(CO)(PPh3)2(I) with a mixture of carbon monoxide and oxygen; (III) reacts with triphenylphosphine to produce (I).