Models for enzyme–substrate complexes: kinetics of hydrolysis of bicyclic immonium ether perchlorates
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700000900
Abstract
The rates of hydrolysis of bicyclic immonium ether perchlorates have been measured and the results have been interpreted in terms of unstable cyclol intermediates; on reaction with sodium methoxide the perchlorates yielded bicyclic lactam acetals.
