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Formation of α-dimethylamino-α-methylthio-carbene. Carbene-induced isomerization of dimethyl maleate
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700000907
Abstract

Deprotonation of (Me2N)(MeS)CH+I with NaH produces an N,S-carbene: dimethyl maleate undergoes isomerization during the carbene-forming reaction.

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