Dehydro-NN′N″-tricyclohexylguanidinohexacarbonyldi-iron(0), a novel carbene generator
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700000932
Abstract
The complex Fe2(dtg)(CO)6 reacts with CHCl3 in the presence of EtOH to give products with olefins which show that dichlorocarbene has been added across the C–C double bond and/or inserted in C–H bonds.