A new reaction of alk-2-ynyl complexes of iron with N-thionylaniline
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700000951
Abstract
The reactions of C5H5Fe(CO)2CH2CCR [R = Me, CH2Fe(CO)2(C5H5), or Ph] with N-thionylaniline afford novel metal vinyl complexes C5H5Fe(CO)2[graphic omitted]H2 which contain a 1,2-thiazine 1-oxide cyclic system.
![[triple bond, length as m-dash]](http://hg.y866.cn/compound/lib/scimg/usr/1/C29700000951.jpg)
CR [R = Me, CH2Fe(CO)2(C5H5), or Ph] with N-thionylaniline afford novel metal vinyl complexes C5H5Fe(CO)2[graphic omitted]H2 which contain a 1,2-thiazine 1-oxide cyclic system.
