Two new methods for the introduction of a 3,3-dimethylallyl group ortho- to a phenolic hydroxy-group and their application to the synthesis of dihydro-6-deoxyjacareubin
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29690001505
Abstract
Two unambiguous methods have been developed for the introduction of the 3,3-dimethylallyl group ortho- to a phenolic hydroxy-group and both methods have been used to prepare dihydro-6-deoxyjacareubin.