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ortho Conjugate addition of benzyl grignards—a remarkable copper effect
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29690001107
Abstract

ortho-1,4-Addition is the predominant reaction between m-methoxybenzyl Grignard reagent and methyl vinyl ketone but it is sharply reduced in the presence of copper(I) chloride.

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