Enantiospecific 6π-photocyclization of atropisomeric α-substituted acrylanilides in the solid-state: role of crystalline confinement on enantiospecificity†‡,10.1039/C1PP05057E

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Enantiospecific 6π-photocyclization of atropisomeric α-substituted acrylanilides in the solid-state: role of crystalline confinement on enantiospecificity†‡

Anoklase Jean-Luc Ayitou,Nandini Vallavoju,Angel Ugrinov,J. Sivaguru

Photochemical & Photobiological Sciences Pub Date : 03/23/2011 00:00:00 , DOI:10.1039/C1PP05057E

Abstract

Direct irradiation of optically-pure axially-chiral α-substituted acrylanilides in the crystalline state leads to 3,4-dihydro-2-quinolin-2-one photoproduct with an enantiomeric ratio of 85 : 15 while a racemic mixture of photoproduct is observed in solution.