Auxiliary donors for phenothiazine sensitizers for dye-sensitized solar cells – how important are they really?†
Audun Formo Buene,Eline Ekornhol Ose,Ane Garborg Zakariassen,Anders Hagfeldt,Bård Helge Hoff
Journal of Materials Chemistry A Pub Date : 02/22/2019 00:00:00 , DOI:10.1039/C9TA00472F
Abstract

Auxiliary donors are common design motifs for phenothiazine sensitizers for dye-sensitized solar cells. Despite this, there are only a few reports on their overall contribution to the photon-to-electron conversion efficiency. Twelve sensitizers have been prepared and investigated, including ten different auxiliary donors in addition to a control with no auxiliary donor. The various auxiliary donors improved the PCE by a modest 4–11%, and pyrene (AFB-19) was determined to be the most efficient auxiliary donor, with the best cell delivering a PCE of 5.36%. Included in the dye series was also the champion dye within the phenothiazine class. With a reported PCE of 12.1%, it would be an excellent phenothiazine reference dye. The high VOC of 0.83 V of this dye is worth further investigation, but the absorption and photovoltaic performance in this work does not correlate with the previously reported PCE of 12.1%.

Graphical abstract: Auxiliary donors for phenothiazine sensitizers for dye-sensitized solar cells – how important are they really?