Battlement-shaped 1D coordination polymer based on a bis(N-methylimidazole-2-yl)butadiyne ligand†,10.1039/C3CE41652F

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Battlement-shaped 1D coordination polymer based on a bis(N-methylimidazole-2-yl)butadiyne ligand†

Thomas Waidmann,Nico Fritsch,Johannes Tucher,Marc Rudolf,Felix Glaser,Dirk M. Guldi,Nicolai Burzlaff

CrystEngComm Pub Date : 08/21/2013 00:00:00 , DOI:10.1039/C3CE41652F

Abstract

Bis(N-methylimidazole-2-yl)butadiyne (bmib) has been prepared starting from N-methylimidazole following two different pathways. Bmib fluoresces and is capable of forming 1D coordination polymers by clamping together metal units. The molecular structure of a zinc coordination polymer based on bmib and zinc acetate resembles a battlement of a fortress.