Bispidine as a helix inducing scaffold: examples of helically folded linear peptides†,10.1039/C3CC45649H

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Bispidine as a helix inducing scaffold: examples of helically folded linear peptides†

V. Haridas,Sandhya Sadanandan,M. V. S. Gopalakrishna,M. B. Bijesh,Ram. P. Verma,Srinivas Chinthalapalli,Ashutosh Shandilya

Chemical Communications Pub Date : 10/08/2013 00:00:00 , DOI:10.1039/C3CC45649H

Abstract

We designed and synthesized bispidine-anchored peptides and showed that these peptides as small as B3 (containing four chiral α-amino acid residues) adopt a right handed helical conformation. Bispidine anchored linear peptide B3 adopts a helical conformation in solution and in the solid state.